catena-Poly[[diaqua(2,2′-bipyridine-κ2 N,N′)zinc]-μ-2,2′-[1,4-phenylenebis(sulfanediyl)]diacetato-κ2 O:O′]
نویسندگان
چکیده
In the polymeric title complex, [Zn(C(10)H(8)O(4)S(2))(C(10)H(8)N(2))(H(2)O)(2)](n), the Zn(2+) ion lies on a twofold rotation axis and exhibits an octa-hedral environment, in which it is coordinated by two trans O atoms from two symmetry-related 2,2'-[1,4-phenyl-enebis(sulfanedi-yl)]diacetate anions, two N atoms from one 2,2'-bipyridine ligand, and two cis O atoms from water mol-ecules. The dihedral angle between the two pyridine rings is 11.5 (1)°. Adjacent Zn(2+) ions are bridged in a monodentate manner by the diacetate anions, forming a chain structure extending parallel to [101], and are further linked into the final three-dimensional structure by O-H⋯O hydrogen bonds between the coordinating water mol-ecules as donor and the non-coordinating carboxyl-ate O atoms as acceptor atoms.
منابع مشابه
Poly[diaqua(μ-4,4′-bipyridine-κ2 N:N′)[μ-2,2′-(p-phenylenedioxy)diacetato-κ2 O:O′]cadmium]
In the title compound, [Cd(C(10)H(8)O(6))(C(10)H(8)N(2))(H(2)O)(2)](n), the Cd(II) ion has inversion symmetry and is coordinated by O atoms from two water mol-ecules and two bridging 2,2'-(μ-p-phenyl-enedi-oxy)diacetate ligands and two N atoms from two 4,4'-bipyridine ligands, giving a slightly distorted octa-hedral geometry. The diacetate and 4,4'-bipyridine ligands also lie across inversion c...
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